The oxidation of toluene on various molybdenum-containing catalysts
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چکیده
منابع مشابه
The Oxidation of Toluene on Various Molybdenum-Containing Catalysts
The activities for the vapour-phase oxidation of toluene of various molybdenum-containing catalysts have been measured in a flow microreactor operating at 1 atm pressure. The catalysts comprised (a) unsupported crystalline MOO,, (b) MO oxide monolayers on A&O,, CeO,, TiO,, and ZrO, supports, and (c) Al-, Ce-, and Zr-molybdate salts. The rates of oxidation of toluene per unit surface area on the...
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Gas-solid heterogeneous photooxidation of toluene over TiO2 catalyst was studied to investigate the factors controlling the catalytic activities. The toluene photooxidation behavior on TiO2 was strongly affected by the formation and oxidation behavior of intermediate compounds on TiO2, and their accumulation decreased the reaction rate for toluene photooxidation. The formation and oxidation beh...
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The oxidation of toluene in air was investigated using a dielectric barrier discharge (DBD) combined with a Pd/Al2O3 catalyst. When using only plasma, rather low selectivity toward CO2 was obtained: 32-35%. By filling the DBD reactor with Pd/Al2O3 catalyst the CO2 selectivity was significantly enhanced (80-90%), however, a large amount of toluene was desorbed from the catalyst when the discharg...
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For the first time, dioxomolybdenum(VI) complex with the general formula [MoO2L2] containing a N-O bidentate ligands (HL=2-(o-aminophenyl)- benzimidazole) has been used for the oxidation of sulfides. Elemental analyses (carbon, hydrogen, nitrogen), FT-IR and Uv-Visble spectra and 1HNMR analysis agree well with the proposed stoicheiometry of the complex [MoO...
متن کاملEfficient oxidation of sulfides using a molybdenum(VI)–dioxo complex containing an benzimidazole ligand
For the first time, dioxomolybdenum(VI) complex with the general formula [MoO2L2] containing a N-O bidentate ligands (HL=2-(o-aminophenyl)- benzimidazole) has been used for the oxidation of sulfides. Elemental analyses (carbon, hydrogen, nitrogen), FT-IR and Uv-Visble spectra and 1HNMR analysis agree well with the proposed stoicheiometry of the complex [MoO...
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ژورنال
عنوان ژورنال: Journal of Catalysis
سال: 1981
ISSN: 0021-9517
DOI: 10.1016/0021-9517(81)90041-5